Hexagonal mesoporous germanium

被引：143

作者：

Armatas, Gerasimos S. ^{[1
]}

Kanatzidis, Mercouri G. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

SCIENCE | 2006年 / 313卷 / 5788期

关键词：

D O I：

10.1126/science.1130101

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The blending of mesoporosity with the properties of semiconductors promises new types of multifunctional nanomaterials. It would be particularly interesting to combine the shape selectivity of a mesoporous oxide with the electronic and photonic characteristics of a useful semiconductor. We demonstrated the synthesis of a mesoporous germanium semiconductor using liquid-crystals-templated chemistry. The template removal was achieved by a two-step ion-exchange thermal procedure. This semiconductive mesoporous form of germanium possesses hexagonal pore ordering with very high surface area and exhibits strongly size-dependent optical properties as well as photoluminescence.

引用

页码：817 / 820

页数：4

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