Synthesis of titanium-containing MCM-41

被引：125

作者：

Koyano, KA ^{[1
]}

Tatsumi, T ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,ENGN RES INST,BUNKYO KU,TOKYO 113,JAPAN

来源：

MICROPOROUS MATERIALS | 1997年 / 10卷 / 4-6期

关键词：

alkene epoxidation; MCM-41; titanium silicate;

D O I：

10.1016/S0927-6513(97)00016-3

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Titanium-containing MCM-41 was prepared from the synthesis gel derived from Ti(OC4H9)(4) and several Si sources. By using tetraethyl orthosilicate (TEOS), which is free from Al and Na, as a silica source, we were able to incorporate titanium into the framework of MCM-41 without the formation of anatase. Ti-MCM-41 was applicable to the oxidation of bulky alkenes with H2O2 or t-butyl hydroperoxide (TBHP) as an oxidant. The stability of Ti-MCM-41 against water was low compared to pure-silica MCM-41. (C) 1997 Elsevier Science B.V.

引用

页码：259 / 271

页数：13

共 47 条

[1] Titanosilicate mesoporous molecular sieve MCM-41: Synthesis and characterization
Alba, MD
Luan, ZH
Klinowski, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (06) : 2178 - 2182
[2] MOLECULAR OR SUPRAMOLECULAR TEMPLATING - DEFINING THE ROLE OF SURFACTANT CHEMISTRY IN THE FORMATION OF MICROPOROUS AND MESOPOROUS MOLECULAR-SIEVES
BECK, JS
VARTULI, JC
KENNEDY, GJ
KRESGE, CT
ROTH, WJ
SCHRAMM, SE
[J]. CHEMISTRY OF MATERIALS, 1994, 6 (10) : 1816 - 1821
[3] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
BECK, JS
VARTULI, JC
ROTH, WJ
LEONOWICZ, ME
KRESGE, CT
SCHMITT, KD
CHU, CTW
OLSON, DH
SHEPPARD, EW
MCCULLEN, SB
HIGGINS, JB
SCHLENKER, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
[4] BELLUSI G, 1991, STUD SURF SCI CATAL, V74, P79
[5] BELLUSSI G, 1991, STUD SURF SCI CATAL, V63, P421
[6] EFFECT OF COUNTERION ON THE SIZE AND CHARGE OF ALKYLTRIMETHYLAMMONIUM HALIDE MICELLES AS A FUNCTION OF CHAIN-LENGTH AND CONCENTRATION AS DETERMINED BY SMALL-ANGLE NEUTRON-SCATTERING
BERR, S
JONES, RRM
JOHNSON, JS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (13) : 5611 - 5614
[7] SYNTHESIS, CHARACTERIZATION, AND CATALYTIC ACTIVITY OF TI-MCM-41 STRUCTURES
BLASCO, T
CORMA, A
NAVARRO, MT
PARIENTE, JP
[J]. JOURNAL OF CATALYSIS, 1995, 156 (01) : 65 - 74
[8] BLEASDALE TA, 1990, STRUCTURE DYNAMICS E, P397
[9] INFRARED SPECTROSCOPIC INVESTIGATION OF TITANIUM IN ZEOLITES - A NEW ASSIGNMENT OF THE 960 CM(-1) BAND
CAMBLOR, MA
CORMA, A
PEREZPARIENTE, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (06) : 557 - 559
[10] SYNTHESIS OF A TITANIUMSILICOALUMINATE ISOMORPHOUS TO ZEOLITE-BETA AND ITS APPLICATION AS A CATALYST FOR THE SELECTIVE OXIDATION OF LARGE ORGANIC-MOLECULES
CAMBLOR, MA
CORMA, A
MARTINEZ, A
PEREZPARIENTE, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) : 589 - 590

← 1 2 3 4 5 →