Conformational analysis of (S,S)-dimethyl-diketopyridino-18-crown-6

被引：11

作者：

Bocskei, Z

Keseru, GM

Menyhard, D

Huszthy, P

Bradshaw, JS

Izatt, RM

机构：

[1] TECH UNIV BUDAPEST, DEPT CHEM INFORMAT TECHNOL, H-1521 BUDAPEST, HUNGARY

[2] EOTVOS LORAND UNIV, DEPT THEORET CHEM, H-1518 BUDAPEST, HUNGARY

[3] TECH UNIV BUDAPEST, DEPT ORGAN CHEM, H-1521 BUDAPEST, HUNGARY

[4] BRIGHAM YOUNG UNIV, DEPT CHEM, PROVO, UT 84602 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195011346

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of (S,S)-dimethyldiketopyridino-18-crown-6, (I), C17H23NO7, an effective host for chiral organic ammonium salts is described. A minimum-energy conformation was obtained by a pseudo-Monte-Carlo conformational search in the gas phase and was compared with the crystal structure. Structural changes in chiral recognition processes are also discussed.

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收藏

页码：463 / 466

页数：4

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