Sugar anomerism -: a short and sweet digression -: Perspective on "The application of ab initio molecular orbital theory to the anomeric effect" -: !Jeffrey GA, !Pople JA, !Radom L (1972) Carbohydr Res 25:117

被引：2

作者：

Cramer, CJ

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Inst Supercomp, Minneapolis, MN 55455 USA

来源：

THEORETICAL CHEMISTRY ACCOUNTS | 2000年 / 103卷 / 3-4期

关键词：

carbohydrate; conformational analysis; stereoelectronic effects; hyperconjugation;

D O I：

10.1007/s002149900068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The subject paper presented the first conformational analysis of the anomeric effect within the context of molecular orbital theory, discussed the utility of Fourier decomposition of a torsional coordinate as a method for analyzing disparate electronic influences on that coordinate, and helped settle debate on the nature of anomeric stabilization.

引用

页码：308 / 310

页数：3

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