Carbodiazenylation of olefins by radical iodine transfer and addition to arenediazonium salts

被引：22

作者：

Blank, Olga ^{[1
]}

Heinrich, Markus R. ^{[1
]}

机构：

[1] Tech Univ Munich, D-85747 Garching, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 2006卷 / 19期

关键词：

anilines; arenediazonium ions; aryl radicals; carbodiazenylation; iodine transfer;

D O I：

10.1002/ejoc.200600528

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbodiazenylation of olefins can be achieved with arenediazonium salts under reductive conditions. The method can be extended to aliphatic substituents when iodine compounds are present in the reaction mixture. Incorporation is achieved through a radical iodine transfer. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

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页码：4331 / 4334

页数：4

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