Abilities of partial least squares (PLS) multivariate calibration in the analysis of a quaternary mixture of sulfonamides

被引：6

作者：

EspinosaMansilla, A ^{[1
]}

Salinas, F ^{[1
]}

Paya, ID ^{[1
]}

机构：

[1] UNIV GRANADA,DEPT ANALYT CHEM,E-18071 GRANADA,SPAIN

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1996年 / 354卷 / 02期

关键词：

D O I：

10.1007/PL00012717

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A quaternary mixture of sulfametazine (SM), sulfaquinoxaline (SQ), sulfatiazole (ST) and sulfamerazine (SR) was resolved by application of a partial least squares (PLS) method. A calibration set of standard samples has been designed. Squared correlation coefficients of 0.9981 for SM, 0.9904 for SR, 0.9993 for SQ and 0.9996 for ST were obtained by using the optimized PLS-1 model. Artificial mixtures of the four sulfonamides were satisfactorily analyzed. The possibility of a simultaneous determination in milk is presented.

引用

页码：245 / 249

页数：5

共 22 条

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