A new nido-5-vertex cluster, phosphacarba-nido-pentaborane, 2-tBu-1,2-PCB3H5

被引：17

作者：

Condick, PN

Fox, MA

Greatrex, R ^{[1
]}

Jones, C

Ormsby, DL

机构：

[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

[3] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 14期

关键词：

D O I：

10.1039/b204409a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gas-phase reaction of the phosphaalkyne P=(CBu)-Bu-t with tetraborane(10), B4H10, yields the nido five-vertex phosphacarbaborane cluster compound 2-Bu-t-1,2-PCB3H5 2 with an unusual P-31 NMR peak shift of -500.5 ppm.

引用

页码：1448 / 1449

页数：2

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