Chemical oxidative polymerization of dodecylbenzenesulfonic acid aniline salt in chloroform

被引：36

作者：

Kuramoto, N

Tomita, A

机构：

来源：

SYNTHETIC METALS | 1997年 / 88卷 / 02期

关键词：

polyaniline and derivatives; dodecylbenzenesulfonic acid; oxidative polymerization;

D O I：

10.1016/S0379-6779(97)03850-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polymerizations of dodecylbenzenesulfonic acid aniline salt (DBSAn) in chloroform using various electron accepters were studied as a function of polymer yield and conductivity. Dichlorodicyanobenzoquinone (DDQ) is an effective oxidant for the polymerization of DBSAn to yield sufficient amount of polyaniline. Suspension polymerization of DBSAn in chloroform with a small amount of water containing ammonium persulfate (APS) as an oxidant was found to yield a homogeneous transparent and green-black suspension containing polyaniline. Polyaniline was found to exhibit strong solvatochromism in aqueous and chloroform solutions.

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收藏

页码：147 / 151

页数：5

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