Transport with time-dependent boundary conditions in a ν-dimensional membrane

被引:11
作者
Ash, R [1 ]
机构
[1] Univ London Imperial Coll Sci & Technol, Dept Chem, Phys Chem Labs, London SW7 2AZ, England
关键词
diffusion; sorption kinetics; theory; time-lags;
D O I
10.1016/j.memsci.2003.11.010
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Following Favre et al. [J. Membr. Sci. 207 (2002) 59], a detailed study has been made of the effect of time-dependence in the boundary conditions upon the four measurable time-lags associated with transport through a membrane. A new procedure for deriving the modified time-lags is presented which encompasses three membrane geometries and a variety of boundary conditions. While the greater part of the treatment involves a constant diffusion coefficient, some attention has been given to the corresponding problem of transport in a slab membrane,governed by a concentration-dependent diffusion coefficient. The application of this procedure to a particular aspect of constant-pressure sorption kinetics is also indicated. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:9 / 18
页数:10
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