Dialkylzincs in radical reactions

被引：57

作者：

Bazin, Samantha ^{[1
]}

Feray, Laurence ^{[1
]}

Bertrand, Michele P. ^{[1
]}

机构：

[1] Univ Paul Cezanne, Lab Chim Mol Organ, UMR 6517, Fac Sci St Jerome, F-13397 Marseille 20, France

来源：

CHIMIA | 2006年 / 60卷 / 05期

关键词：

conjugate addition; dialkylzinc; imines; radical addition; radical initiator; radical-polar crossover reactions;

D O I：

10.2533/000942906777674679

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review describes recent developments in the use of dialkylzincs in radical reactions. In most of the processes reported therein, dialkylzincs act simultaneously as sources of alkyl radicals, as Lewis acids, and as chain transfer agents. A parallel is drawn with the behaviour of trialkylboranes in similar reactions.

引用

收藏

页码：260 / 265

页数：6

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