Layer-by-layer assembled nanocontainers for self-healing corrosion protection

被引:606
作者
Shchukin, Dmitry G. [1 ]
Zheludkevich, Mikhail
Yasakau, Kiryl
Lamaka, Sviatlana
Ferreira, Mario G. S.
Moehwald, Helmuth
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Univ Aveiro, CICECO, Dept Ceram & Glass Engn, P-3810193 Aveiro, Portugal
关键词
D O I
10.1002/adma.200502053
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-healing anticorrosion effect of layer-by-layer (LbL) assembled nano-reservoirs (polyelectrolyte-coated nanoparticles) embedded in a hybrid coating deposited onto an Al alloy is investigated (see figure). The corrosion inhibitor, benzotriazole, is entrapped in the polyelectrolyte at the LbL assembly step; its release is initiated by local pH changes near the corrosion-damaged zones in the alloy. The nanoreservoirs increase long-term corrosion protection of the substrate and provide effective inhibitor storage and its prolonged release on demand.
引用
收藏
页码:1672 / +
页数:8
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