[2,3]-Sigmatropic rearrangement of allylic sulfur ylides derived from trimethylsilyldiazomethane (TMSD)

被引：49

作者：

Aggarwal, VK ^{[1
]}

Ferrara, M ^{[1
]}

Hainz, R ^{[1
]}

Spey, SE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(99)01896-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trimethylsilyldiazomethane reacts with allylic sulfides in the presence of catalytic quantities of Rh-2(OAc)(4) (1 mol%) to give homoallylic sulfides in good yields and with high diastereoselectivity. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：8923 / 8927

页数：5

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