The preparation of polyaniline intercalated MoO3 thin film and its sensitivity to volatile organic compounds

被引:67
作者
Wang, Junzhong [1 ]
Matsubara, Ichiro [1 ]
Murayama, Norimitsu [1 ]
Woosuck, Shin [1 ]
Izu, Noriya [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
关键词
molybdenum oxide; chemical vapour deposition (CVD); polymers; sensors; GAS-SENSING PROPERTIES; COMPOUNDS VOCS; SENSOR ARRAYS; NANOCOMPOSITE; POLY(ANILINE);
D O I
10.1016/j.tsf.2006.02.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyaniline (PANI) intercalated MoO3 thin films with b-axis preferred orientation were obtained by an ex-situ intercalation process. A MoO3 thin film was first deposited on LaAlO3(100) substrate at 500 degrees C by chemical vapour deposition. It was then partly reduced to [Na (H2O)(2)](x)MoO3 after which intercalation of polyaniline into MoO3 by ion-exchange reaction was performed to obtain (PANI)(x)MoO3. The resulting (PANI)(x)MoO3 thin film exhibits an increase in electrical resistivity in response to volatile organic compounds. Good sensitivity and selectivity of (PANI)(x)MoO3 thin film to formaldehyde and acetaldehyde vapours was observed. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:329 / 333
页数:5
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