Propylthiotetramethylcyclopentadienyl complexes of iron, titanium and zirconium. Structural characterization of [eta(5)-C5Me4SCH2CH2CH3](2)TiCl2

被引：10

作者：

Broussier, R

Bourdon, C

Blacque, O

Vallat, A

Kubicki, MM

Gautheron, B

机构：

[1] Lab. de Synthese et d'El., UMR 5632, 21004 Dijon Cedex, 6 boulevard Gabriel

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 538卷 / 1-2期

关键词：

cyclopentadienyl; sulphur; ferrocene; zirconium; titanium;

D O I：

10.1016/S0022-328X(96)06909-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of the propylthio substituted tetramethylcyclopentadienylsodium salt leads to octamethyl-1,1'-di(propylthio)ferrocene and dichlorodi(propylthiotetramethylcyclopentadienyl)zirconium or titanium(IV). The structure of [eta(5)-C5Me4SCH2CH2CH3](2)TiCl2 has been established by X-ray analysis (orthorhombic, Pbca, a = 16.767(1), b = 16.247(3), c = 19.002(3) Angstrom, V = 5176.2(9) Angstrom(3), Z = 8, R-F = 0.052). The complexes have been characterized by H-1 and C-13 NMR and electrochemical studies.

引用

页码：83 / 90

页数：8

共 38 条

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