Synthesis and molecular structure of bis(pyrazoly)hydroborato thallium {[Bp]Tl}2:: A [BpRR′]Tl complex with an unbridged close TlI....TlI contact

被引：37

作者：

Ghosh, P

Rheingold, AL

Parkin, G ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 23期

关键词：

D O I：

10.1021/ic990647o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of the bis(pyrazolyl)hydroborate thallium complex {[Bp]Tl}(2) has been determined by single-crystal X-ray diffraction. The study demonstrates that the structure is comprised of two [Bp]Tl moieties that are separated by a Tl-I... Tl-I distance of 3.7001(6) Angstrom, a value that is shorter than for all other [Bp(RR')]Tl complexes structurally characterized to date.

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页码：5464 / +

页数：5

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