Novel monoanionic tripodal ligands:: methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate (= [MeB(ImN-Me)2(PzR)]-).: Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron

被引：26

作者：

Fujita, K ^{[1
]}

Hikichi, S ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 02期

关键词：

D O I：

10.1039/a908181j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel monoanionic tripodal ligands, [MeB(Im(N-Me))(2)(Pz(R))](-) (=methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate), are synthesized; their mode of coordination to a nickel center depends on the steric congestion around the boron centers.

引用

页码：117 / 119

页数：3

共 20 条

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