Multifunctional dual Na3V2(PO4)2F3 cathode for both lithium-ion and sodium-ion batteries

被引:85
作者
Song, Weixin [1 ]
Ji, Xiaobo [1 ]
Wu, Zhengping [1 ]
Zhu, Yirong [1 ]
Li, Fangqian [1 ]
Yao, Yinpeng [1 ]
Banks, Craig E. [2 ]
机构
[1] Cent S Univ, Minist Educ, Coll Chem & Chem Engn, Key Lab Resources Chem Nonferrous Met, Changsha, Hunan, Peoples R China
[2] Manchester Metropolitan Univ, Fac Sci & Engn, Sch Sci & Environm, Div Chem & Environm Sci, Manchester M1 5GD, Lancs, England
来源
RSC ADVANCES | 2014年 / 4卷 / 22期
关键词
ELECTRICAL ENERGY-STORAGE; ELECTRODE MATERIALS; PERFORMANCE;
D O I
10.1039/c3ra47878e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Na3V2(PO4)(2)F-3 with a NASICON-type structure is shown to be synthesised with the particle surface found to be coated with amorphous carbon with its thickness in the range of 25-32 nm. The crystallographic planes (hkl) are labelled according to Density Functional Theory (DFT) calculations towards the as-prepared Na3V2(PO4)(2)F-3. The performances of Na3V2(PO4)(2)F-3 have been investigated in lithium-and sodium-ion batteries, exhibiting a specific capacity of 147 mA h g(-1) with an average discharge plateau around 4 V vs. Li+/Li, and 111.5 mA h g(-1) with three discharge plateaus in sodium-ion batteries. A predominant Li ion insertion mechanism is verified by comparing the redox potentials from CV and charge/discharge curves. It is found that the main migration from/into the crystallographic sites of Na3V2(PO4)(2)F-3 of Li ions is favoured to obtain satisfactory properties by a two-step process, while the Na ions are found to require three steps. The stable and three-dimensional open framework of Na3V2(PO4)(2)F-3 is considered to be vital for the excellent C-rate and cycling performances, as well as the fast ion diffusion with a magnitude of 10(-11) cm(2) s(-1), which could demonstrate that Na3V2(PO4)(2)F-3 is a multifunctional dual cathode for both lithium and sodium ion batteries and capable to be a promising candidate in the construction of high-energy batteries.
引用
收藏
页码:11375 / 11383
页数:9
相关论文
共 36 条
[1]   LiMnPO4 - A next generation cathode material for lithium-ion batteries [J].
Aravindan, Vanchiappan ;
Gnanaraj, Joe ;
Lee, Yun-Sung ;
Madhavi, Srinivasan .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (11) :3518-3539
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]   Hybrid-ion - A lithium-ion cell based on a sodium insertion material [J].
Barker, J ;
Gover, RKB ;
Burns, P ;
Bryan, AJ .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (04) :A190-A192
[4]   Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors [J].
Choi, Nam-Soon ;
Chen, Zonghai ;
Freunberger, Stefan A. ;
Ji, Xiulei ;
Sun, Yang-Kook ;
Amine, Khalil ;
Yushin, Gleb ;
Nazar, Linda F. ;
Cho, Jaephil ;
Bruce, Peter G. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (40) :9994-10024
[5]   Li2NaV2(PO4)3:: A 3.7 V lithium-insertion cathode with the rhombohedral NASICON structure [J].
Cushing, BL ;
Goodenough, JB .
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (02) :176-181
[6]   Na3V2(PO4)3 as cathode material for hybrid lithium ion batteries [J].
Du, Ke ;
Guo, Hongwei ;
Hu, Guorong ;
Peng, Zhongdong ;
Cao, Yanbing .
JOURNAL OF POWER SOURCES, 2013, 223 :284-288
[7]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[8]   A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries [J].
Ellis, B. L. ;
Makahnouk, W. R. M. ;
Makimura, Y. ;
Toghill, K. ;
Nazar, L. F. .
NATURE MATERIALS, 2007, 6 (10) :749-753
[9]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[10]   V2(PO4)3 - A NOVEL NASICON-TYPE VANADIUM PHOSPHATE SYNTHESIZED BY OXIDATIVE DEINTERCALATION OF SODIUM FROM NA3V2(PO4)3 [J].
GOPALAKRISHNAN, J ;
RANGAN, KK .
CHEMISTRY OF MATERIALS, 1992, 4 (04) :745-747