EIS study of the codeposition of SiC powder with nickel in a Watts bath

被引:5
作者
Masalski, J
Szczygiel, B
Gluszek, J
机构
[1] Wroclaw Tech Univ, Fac Chem, Dept Surface Engn & Catalysis, PL-50370 Wroclaw, Poland
[2] Wroclaw Tech Univ, Dept Tech Electrochem & Corros Met, PL-50370 Wroclaw, Poland
来源
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING | 2002年 / 80卷
关键词
electrochemical impedance spectroscopy; composite coating; nickel plating; silicon carbide;
D O I
10.1080/00202967.2002.11871443
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The results of impedance investigations of the nickel electrocrystallisation from the Watts baths (with additions of a wetting substance - sodium dodecyl sulphate and of brightening components 2-butyne-1, 4-diol and saccharine), containing SiC powder are presented. The suggested equivalent circuit consists of three resistance and two capacitance elements. The influence of organic additions and silicon carbide powder on the electrolyte resistance (R1), the charge transfer resistance (R3), the desorption resistance (R4), the double layer capacitance (C2) and the pseudo-capacitance (C5) of adsorbed intermediates has been established.
引用
收藏
页码:101 / 104
页数:4
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