Polyoxometalate-diphosphate complexes.: 5.: Cigar-shaped 30-molybdobispyrophosphate:: Structure of (N(C4H9)4)2H9[{(P2O7)Mo15O45}2][PMo12O40]

被引：50

作者：

Kortz, U ^{[1
]}

机构：

[1] Amer Univ Beirut, Dept Chem, Beirut, Lebanon

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 03期

关键词：

D O I：

10.1021/ic9907258

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thenovel, dimeric polyoxometalate [{(P2O7)Mo15O45}2]8- has been characterized by 31P NMR spectroscopy and single-crystal X-ray diffraction. The 30-molybdobispyrophosphate contains two eclipsed diphosphate ions with linear P-O-P bonds (180.0(10)°). The polyanion can be viewed as a fused dimer of two lacunary [(P2O7)Mo15O48] moieties leading to a cigar-shaped structure with four belts and two caps.

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页码：623 / 624

页数：2

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