Simulating polymer liquid crystals

被引:15
作者
Bladon, P [1 ]
Frenkel, D [1 ]
机构
[1] FOM, INST ATOM & MOL PHYS, NL-1098 SJ AMSTERDAM, NETHERLANDS
关键词
D O I
10.1088/0953-8984/8/47/043
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A model suitable for simulating lyotropic polymer liquid crystals (PLCs) is described. By varying the persistence length between infinity and 25, the effect of increasing flexibility on the nematic-smectic transition of a PLC with a length-to-width ratio L/D = 6 is investigated. It is found that increasing flexibility shifts the formation of a smectic phase to higher densities. Comparison is made with a recent theory of the nematic-smectic transition of slightly flexible rods.
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页码:9445 / 9449
页数:5
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