Atomic force and scanning electron microscopic investigation of the in operandi creation of selective sites on MoO3 mixed with alpha-Sb2O4 in the isobutene to methacrolein oxidation

被引：28

作者：

Gaigneaux, EM ^{[1
]}

Ruiz, P ^{[1
]}

Wolf, EE ^{[1
]}

Delmon, B ^{[1
]}

机构：

[1] UNIV NOTRE DAME,DEPT CHEM ENGN,NOTRE DAME,IN 46556

来源：

APPLIED SURFACE SCIENCE | 1997年 / 121卷

关键词：

remote control mechanism; spillover oxygen; MoO3; isobutene oxidation; nanometric reconstruction; AFM;

D O I：

10.1016/S0169-4332(97)00365-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We show that the creation of selective sites on MoO3 due to remote control effects, has, as a counterpart, the spillover-induced reconstruction of the non-selective (010) faces of MoO3 crystals in selective (100) pits and steps. The phenomenon is observed both at the micrometric scale, by SEM, and at the nanometric scale, by AFM. (C) 1997 Elsevier Science B.V.

引用

页码：552 / 557

页数：6

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[2]

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[3]

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