Novel tungsten calix[8]arene complexes

被引：20

作者：

Gibson, VC

Redshaw, C ^{[1
]}

Elsegood, MRJ

机构：

[1] Univ E Anglia, Sch Chem Sci, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[3] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 11期

关键词：

D O I：

10.1039/b201777f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

p-tert-Butylcalix[8] areneH(8) reacts with WCl6 forming a number of new metallocalix[8] arenes, one of which is reduced to give the first example of a metal-metal triple bond supported by a large calixarene ligand; the degree of metallation and conformations adopted by the newly generated metallocalix[8] arene systems are determined by single crystal X-ray diffraction.

引用

收藏

页码：1200 / 1201

页数：2

相关论文

共 20 条

[1] DIMOLYBDENUM(II) CALIXARENE COMPLEXES - SYNTHESIS, STRUCTURE, RAMAN-SPECTROSCOPY, AND BONDING [J].

ACHO, JA ;

REN, T ;

YUN, JW ;

LIPPARD, SJ .

INORGANIC CHEMISTRY, 1995, 34 (21) :5226-5233

[2] CALIXARENE COMPLEXES OF THE MOLYBDENUM-MOLYBDENUM QUADRUPLE BOND [J].

ACHO, JA ;

LIPPARD, SJ .

INORGANICA CHIMICA ACTA, 1995, 229 (1-2) :5-8

[3]

BOTT SG, 1986, CHEM COMMUN, P610

[4]

*BRUK AXS INC, 1994, SMART SAINT SOFTWARE

[5] Preparation and characterization of the kinetic and thermodynamic isomers of dinuclear molybdenum and tungsten complexes with metal-metal triple bonds supported by p-tert-butylcalix[4]arene anions [J].

Chisholm, MH ;

Folting, K ;

Streib, WE ;

Wu, DD .

CHEMICAL COMMUNICATIONS, 1998, (03) :379-380

[6] Synchrotron chemical crystallography [J].

Clegg, W .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (19) :3223-3232

[7] A novel titanium-oxygen ladder structure supported by calix[4]arene ligands, characterised by synchrotron crystallography [J].

Clegg, W ;

Elsegood, MRJ ;

Teat, SJ ;

Redshaw, C ;

Gibson, VC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18) :3037-3039

[8] Control of ligand-metal interaction at the lower rim of p-tert-butylcalix[5]arene [J].

Fan, MM ;

Zhang, HM ;

Lattman, M .

CHEMICAL COMMUNICATIONS, 1998, (01) :99-100

[9] Tungsten-tungsten multiple-bond functionalities supported by a polyoxo surface modeled by calix[4]arene [J].

Giannini, L ;

Solari, E ;

Floriani, C ;

Re, N ;

Chiesi-Villa, A ;

Rizzoli, C .

INORGANIC CHEMISTRY, 1999, 38 (07) :1438-1445

[10] Metal-metal multiple bonds formed across two tungsten-calix[4]arenes by a reductive coupling reaction [J].

Giannini, L ;

Solari, E ;

ZanottiGerosa, A ;

Floriani, C ;

ChiesiVilla, A ;

Rizzoli, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (07) :753-754