Structural and pH control on the electronic communication between two identical ferrocene sites

被引：35

作者：

Alvarez, J

Kaifer, AE ^{[1
]}

机构：

[1] Univ Miami, Ctr Supramol Sci, Coral Gables, FL 33124 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 26期

关键词：

D O I：

10.1021/om990678r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a new type of dinuclear ferrocene compound containing a -CH2-N(R)-CH2-bridge is reported. These new dinuclear ferrocenes exhibit a moderate degree of electronic communication between the two ferrocene subunits, which is disrupted by protonation or N-methylation of the bridge's tertiary nitrogen atom.

引用

页码：5733 / 5734

页数：2

共 6 条

[1] Metal-metal interactions in linked metallocenes [J].