Surprising electronic-magnetic properties of close-packed organized organic layers

被引：38

作者：

Vager, Z

Naaman, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Dept Particle Phys, IL-76100 Rehovot, Israel

来源：

CHEMICAL PHYSICS | 2002年 / 281卷 / 2-3期

基金：

以色列科学基金会;

关键词：

D O I：

10.1016/S0301-0104(02)00374-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Close-packed organized organic monolayers are finding their place in many applications and specifically in molecular electronic related functions. As a result, the relation between the properties of the single molecule and of the molecule imbedded within the monolayer is of importance. Here it is shown that upon formation of the layer the molecular electric dipole is reduced and is independent of the free molecules' electric dipole. Its upper bound value is derived from the thin film property of dielectric breakdown. Moreover, when the molecules in the layer are homochiral, the monolayer may have appreciable magnetic properties. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：305 / 309

页数：5

共 35 条

[1] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].