The crystal structure of [Cu(Ph(2)bipy)(2)][BF4]center dot CH2Cl2 (Ph(2)bipy=6,6'-diphenyl-2,2'-bipyridine)

被引：12

作者：

Bardwell, DA ^{[1
]}

Jeffery, JC ^{[1
]}

Otter, CA ^{[1
]}

Ward, MD ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 02期

关键词：

D O I：

10.1016/0277-5387(95)00260-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure, of the title compound has been determined. The normal four-coordinate geometry of [Cu(NN)(2)](+) cations (where NN denotes an alpha,alpha'-diimine chelate) is highly distorted, with a wide spread of bond lengths and angles, due to the presence of one strong intramolecular pi-stacking, interaction between a phenyl ring of one ligand and the coordinated bipyridyl fragment of the other.

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页码：191 / 194

页数：4

相关论文

共 15 条

[1] PARTIALLY ENCAPSULATED COPPER(I) COMPLEXES OF MONO(O-ARYL) SUBSTITUTED DERIVATIVES OF 2,2'-BIPYRIDINE AND 1,10-PHENANTHROLINE [J].

BARDWELL, DA ;

THOMPSON, AMWC ;

JEFFERY, JC ;

TILLEY, EEM ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (05) :835-841

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(6,6'-DIMETHYL-2,2'-BIPYRIDYL)COPPER(I) TETRAFLUOROBORATE [J].

BURKE, PJ ;

MCMILLIN, DR ;

ROBINSON, WR .

INORGANIC CHEMISTRY, 1980, 19 (05) :1211-1214

[3] MOLECULAR-STRUCTURE OF A CATENAND AND ITS COPPER(I) CATENATE - COMPLETE REARRANGEMENT OF THE INTERLOCKED MACROCYCLIC LIGANDS BY COMPLEXATION [J].

CESARIO, M ;

DIETRICHBUCHECKER, CO ;

GUILHEM, J ;

PASCARD, C ;

SAUVAGE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (05) :244-247

[4]

DIETRICHBUCHECKER CO, 1984, NOUV J CHIM, V8, P573

[5]

FEDERLIN P, 1990, NEW J CHEM, V14, P9

[6] COPPER(I) AND COPPER(II) COMPLEXES OF ENTWINED OR INTERLOCKED PHENANTHROLINE TYPE LIGANDS - ESR AND CRYSTALLOGRAPHIC INVESTIGATIONS [J].

GEOFFROY, M ;

WERMEILLE, M ;

BUCHECKER, CO ;

SAUVAGE, JP ;

BERNARDINELLI, G .

INORGANICA CHIMICA ACTA, 1990, 167 (02) :157-164

[7]

HAMALAINEN R, 1979, CRYST STRUCT COMMUN, V8, P75

[8]

Horvath O., 1993, CHARGE TRANSFER PHOT

[9] CHARGE-TRANSFER ABSORPTION AND EMISSION OF CU(NN)2+ SYSTEMS [J].

ICHINAGA, AK ;

KIRCHHOFF, JR ;

MCMILLIN, DR ;

DIETRICHBUCHECKER, CO ;

MARNOT, PA ;

SAUVAGE, JP .

INORGANIC CHEMISTRY, 1987, 26 (25) :4290-4292

[10] AUTOREDUCTION OF COPPER(II) COMPLEXES OF 6,6'-DIALKYL-2,2'-BIPYRIDINE AND CHARACTERIZATION OF THEIR COPPER(I) COMPLEXES [J].

KITAGAWA, S ;

MUNAKATA, M ;

HIGASHIE, A .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (01) :79-84