Synthesis of propargylic fluorides from allenylsilanes

被引：28

作者：

Carroll, Laurence ^{[1
]}

Pacheco, Ma Carmen ^{[1
]}

Garcia, Ludivine ^{[1
]}

Gouverneur, Veronique ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 39期

关键词：

D O I：

10.1039/b610013a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

引用

页码：4113 / 4115

页数：3

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