Strong Hydrogen Binding within a 3D Microporous Metal-Organic Framework

被引：85

作者：

Zhong, Di-Chang

Lin, Jian-Bin

Lu, Wen-Guan

Jiang, Long

Lu, Tong-Bu ^{[1
]}

机构：

[1] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 18期

关键词：

H-2; ADSORPTION; SURFACE-AREA; STORAGE; CATENATION; SORPTION; SITES;

D O I：

10.1021/ic900968d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D microporous cadmium(II) metal-organic framework based on 1H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ring-decorated inner surface of the pores.

引用

页码：8656 / 8658

页数：3

共 37 条

[1] On the mechanism of hydrogen storage in a metal-organic framework material
Belof, Jonathan L.
Stern, Abraham C.
Eddaoudi, Mohamed
Space, Brian
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) : 15202 - 15210
[2] A route to high surface area, porosity and inclusion of large molecules in crystals
Chae, HK
Siberio-Pérez, DY
Kim, J
Go, Y
Eddaoudi, M
Matzger, AJ
O'Keeffe, M
Yaghi, OM
[J]. NATURE, 2004, 427 (6974) : 523 - 527
[3] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material
Chen, Banglin
Zhao, Xuebo
Putkham, Apipong
Hong, Kunlun
Lobkovsky, Emil B.
Hurtado, Eric J.
Fletcher, Ashleigh J.
Thomas, K. Mark
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) : 6411 - 6423
[4] Hydrogen adsorption in an interpenetrated dynamic metal-organic framework
Chen, Banglin
Ma, Shengqian
Zapata, Fatima
Lobkovsky, Emil B.
Yang, Jun
[J]. INORGANIC CHEMISTRY, 2006, 45 (15) : 5718 - 5720
[5] DANIELS F, 1962, EXPT PHYS CHEM
[6] Expanded sodalite-type metal-organic frameworks:: Increased stability and H2 adsorption through ligand-directed catenation
Dinca, Mircea
Dailly, Anne
Tsay, Charlene
Long, Jeffrey R.
[J]. INORGANIC CHEMISTRY, 2008, 47 (01) : 11 - 13
[7] High-enthalpy hydrogen adsorption in cation-exchanged variants of the microporous metal-organic framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2
Dinca, Mircea
Long, Jeffrey R.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (36) : 11172 - 11176
[8] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites
Dinca, Mircea
Dailly, Anne
Liu, Yun
Brown, Craig M.
Neumann, Dan. A.
Long, Jeffrey R.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) : 16876 - 16883
[9] Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal-organic framework
Dinca, Mircea
Han, Won Seok
Liu, Yun
Dailly, Anne
Brown, Craig M.
Long, Jeffrey R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (09) : 1419 - 1422
[10] Microporous metal-organic frameworks incorporating 1,4-benzeneditetrazolate: Syntheses, structures, and hydrogen storage properties
Dinca, Mircea
Yu, Anta F.
Long, Jeffrey R.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (27) : 8904 - 8913

← 1 2 3 4 →