Vibrational investigation of the stretching region of bromate ion in solution

被引：12

作者：

Alves, WA ^{[1
]}

Faria, RB ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, Dept Quim Inorgan, BR-21945970 Rio De Janeiro, Brazil

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2002年 / 58卷 / 07期

关键词：

IR spectra; Raman spectra; bromate;

D O I：

10.1016/S1386-1425(01)00589-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The splitting of nu(1) (794 cm(-1)) and nu(3) (805 cm(-1)) modes in the stretching region of the bromate (C-3nu) was observed for the first time in dimethyl sulfoxide (DMSO) using vibrational spectroscopy. Depolarization measurements allowed to assign the asymmetric and symmetric modes in solution. The band at 805 cm(-1) that has been attributed to the symmetric stretching mode (A(1)) corresponds in fact to the asymmetric stretching mode (E) and the band at 794 cm(-1) corresponds to the symmetric stretching mode (A(1)). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：1395 / 1399

页数：5

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