Nanocrystallization of Cu-(Zr or Hf)-Ti metallic glasses

被引：69

作者：

Louzguine, DV ^{[1
]}

Inoue, A ^{[1
]}

机构：

[1] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

JOURNAL OF MATERIALS RESEARCH | 2002年 / 17卷 / 08期

基金：

日本学术振兴会;

关键词：

D O I：

10.1557/JMR.2002.0312

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Crystallization of the Cu60Zr30Ti10 and Cu60Hf25Ti15 metallic glasses was studied by x-ray diffractometry, transmission electron microscopy, differential scanning and isothermal calorimetries. Metastable Cu-Zr-Ti and Cu-Hf-Ti cubic phases primarily precipitated in the Cu60Zr30Ti10 and Cu60Hf25Ti15 metallic glasses. The Cu60Zr30Ti10 metallic glass crystallizes with low energy barrier for nucleation while crystallization of the Cu60Hf25Ti15 metallic glass takes place by nucleation and diffusion-controlled growth of cubic Cu-Hf-Ti phase particles with constant nucleation rate. The Cu60Hf25Ti15 metallic glass is characterized by a low activation energy for nucleation.

引用

页码：2112 / 2120

页数：9

共 31 条

[1]

ACKERMANN RJ, 1977, J AM CERAM SOC, V60, P341, DOI 10.1111/j.1151-2916.1977.tb15557.x

[2] CRYSTALLIZATION CHARACTERISTICS OF CU-ZR METALLIC GLASSES FROM CU70ZR30 TO CU25ZR75 [J].

ALTOUNIAN, Z ;

TU, GH ;

STROMOLSEN, JO .

JOURNAL OF APPLIED PHYSICS, 1982, 53 (07) :4755-4760

[3] Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184

[4] PHASE-SEPARATION IN VAPOR QUENCH SYNTHESIZED NONCRYSTALLINE COPPER ZIRCONIUM ALLOYS [J].

BARBEE, TW ;

WALMSLEY, RG ;

MARSHALL, AF ;

KEITH, DL ;

STEVENSON, DA .

APPLIED PHYSICS LETTERS, 1981, 38 (03) :132-135

[5]

CHRISTIAN JW, 1975, THEORY TRANSFORMATIO, P542

[6]

DEBOER FR, 1988, COHESION METALS, P250

[7] Crystallization behavior and phase formation in Zr-Al-Cu-Ni metallic glass containing oxygen [J].

Eckert, J ;

Mattern, N ;

Zinkevitch, M ;

Seidel, M .

MATERIALS TRANSACTIONS JIM, 1998, 39 (06) :623-632

[8]

ELLIOTT JF, 1976, METALL TRANS B, V7, P17, DOI 10.1007/BF02652816

[9] Stabilization of metallic supercooled liquid and bulk amorphous alloys [J].

Inoue, A .

ACTA MATERIALIA, 2000, 48 (01) :279-306

[10] High-strength Cu-based bulk glassy alloys in Cu-Zr-Ti and Cu-Hf-Ti ternary systems [J].

Inoue, A ;

Zhang, W ;

Zhang, T ;

Kurosaka, K .

ACTA MATERIALIA, 2001, 49 (14) :2645-2652

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