Stereocontrolled access to carba-C-disaccharides via functionalized dienylsilanes.

被引：40

作者：

Angelaud, R ^{[1
]}

Landais, Y ^{[1
]}

ParraRapado, L ^{[1
]}

机构：

[1] UNIV LAUSANNE,INST CHIM ORGAN,COLL PROPEDEUT,CH-1015 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(97)10389-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report here the total synthesis of a class of Cl --> C6 Carba-C-disaccharide, formed by the association between a 2-deoxyglucose as the sugar unit and a pseudo-pyranose or a pseudo-furanose as the carba-sugar moiety. The carba-sugar fragments were assembled from the corresponding dienylsilanes through a dihydroxylation-cyclopropanation sequence. (C) 1997 Elsevier Science Ltd.

引用

页码：8845 / 8848

页数：4

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