Photocurable membranes for ion-selective light-addressable potentiometric sensor

被引:28
作者
Ermolenko, Y
Yoshinobu, T
Mourzina, Y
Levichev, S
Furuichi, K
Vlasov, Y
Schöning, MJ
Iwasaki, H
机构
[1] Forschungszentrum Julich, Inst Thin Films & Interfaces, D-52425 Julich, Germany
[2] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan
[3] St Petersburg State Univ, Fac Chem, St Petersburg 199034, Russia
[4] Univ Appl Sci Aachen, D-52428 Julich, Germany
关键词
light-addressable potentiometric sensor (LAPS); photocurable membranes; ion-sensitivity;
D O I
10.1016/S0925-4005(02)00056-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new type of light-addressable potentiometric sensor (LAPS) has been developed by elaboration of photocurable ion-sensitive membranes based on matrices of mono- and diacrylates in combination with a silicon-based electrochemical transducer for the purposes of chemical and biochemical analyses. The characteristics of the elaborated K-, Li-, Cs-, Ca- and Mg-LAPS are presented to indicate the potential of the technology developed. For example, the sensitivities of the K- and Li-LAPS were found to be 58 +/- 1 mV/pK and 59 +/- 1 mV/pLi, respectively, over concentration ranges of 10(-5)-10(-1) mol/l. The detection limits were evaluated to be 2 x 10(-6) mol/l of the primary ion. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:79 / 85
页数:7
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