Performance evaluation of triethanolamine as corrosion inhibitor for magnesium alloy in 3.5 wt% NaCl solution

被引:56
作者
Shang, Wei [1 ]
He, Chubin [1 ]
Wen, Yuqing [1 ]
Wang, Yuanyuan [1 ]
Zhang, Zhe [1 ]
机构
[1] Guilin Univ Technol, Guangxi Key Lab Electrochem & Magnetochem Funct M, Coll Chem & Bioengn, Guilin 541004, Peoples R China
基金
中国国家自然科学基金;
关键词
MILD-STEEL CORROSION; SCHIFF-BASE COMPOUNDS; CARBON-STEEL; DOUBLE-LAYER; IRON; ADSORPTION; DERIVATIVES; CAPACITANCE; MECHANISMS; MORPHOLOGY;
D O I
10.1039/c6ra23203e
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
The corrosion inhibition performance of triethanolamine (TEA) with AZ91D magnesium alloy in 3.5 wt% NaCl solution has been studied using an immersion experiment, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, surface analysis, and quantum chemical methods. The results revealed that TEA was a good corrosion inhibitor. The polarization plots indicated that TEA served as a mixed-type inhibitor. The adsorption of TEA molecules was found to follow the Langmuir adsorption isotherm, which was a spontaneous, exothermic process of increased entropy. TEA could considerably improve the corrosion resistance of the Mg alloy in 3.5 wt% NaCl.
引用
收藏
页码:113967 / 113980
页数:14
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