Water transport in the proton exchange-membrane fuel cell: Comparison of model computation and measurements of effective drag

被引:29
作者
Murahashi, Toshiaki [1 ]
Naiki, Masao [1 ]
Nishiyama, Enju [1 ]
机构
[1] Univ Fukui, Dept Elect & Elect Engn, Fukui 9108505, Japan
关键词
proton exchange membrane fuel cell; water transport; water management; net water drag; capillary effect;
D O I
10.1016/j.jpowsour.2006.07.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Water transport through the membrane of a PEMFC was investigated by measurement of the net drag under various feed gas humidity. Measured data were compared with computed results obtained using a two-dimensional cell model. Considering the change in the gas content related to the flow configuration, the humidity of the supply gas, reaction rates, and the mass balance of each gas species were derived at five sections along the flow channels. By solving these mass balance equations, the water transport rates and current density distribution were obtained along the flow channels for various feed gas humidity. The results for net drag computed from the model show a similar tendency, but are slightly higher than the measured values. This suggests that there is a certain resistance related to water transport at the cathode membrane interface in association with water production. The cause of this water transport resistance is discussed. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1130 / 1136
页数:7
相关论文
共 18 条
[1]  
ADAMSON AD, 1960, PHYS CHEM SURFACES, P58
[2]  
ADAMSON AD, 1960, PHYS CHEM SURFACES, P358
[3]   MATHEMATICAL-MODEL OF A GAS-DIFFUSION ELECTRODE BONDED TO A POLYMER ELECTROLYTE [J].
BERNARDI, DM ;
VERBRUGGE, MW .
AICHE JOURNAL, 1991, 37 (08) :1151-1163
[4]   Operating proton exchange membrane fuel cells without external humidification of the reactant gases - Fundamental aspects [J].
Buchi, FN ;
Srinivasan, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (08) :2767-2772
[5]   Distributed performance of polymer electrolyte fuel cells under low-humidity conditions [J].
Dong, Q ;
Mench, MM ;
Cleghorn, S ;
Beuscher, U .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2114-A2122
[6]   Three-dimensional numerical simulation of straight channel PEM fuel cells [J].
Dutta, S ;
Shimpalee, S ;
Van Zee, JW .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (02) :135-146
[7]   Investigation of mass-transport limitations in the solid polymer fuel cell cathode - II. Experimental [J].
Ihonen, J ;
Jaouen, F ;
Lindbergh, G ;
Lundblad, A ;
Sundholm, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (04) :A448-A454
[8]   Water transport in the proton-exchange-membrane fuel cell: Measurements of the effective drag coefficient [J].
Janssen, GJM ;
Overvelde, MLJ .
JOURNAL OF POWER SOURCES, 2001, 101 (01) :117-125
[9]   A phenomenological model of water transport in a proton exchange membrane fuel cell [J].
Janssen, GJM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (12) :A1313-A1323
[10]   Nonisothermal modeling of polymer electrolyte fuel cells - I. Experimental validation [J].
Ju, HC ;
Wang, CY ;
Cleghorn, S ;
Beuscher, U .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (08) :A1645-A1653