Preparation of magnetic latexes using styrene monomer

被引:14
作者
Betancourt-Galindo, R
Saldívar-Guerrero, R
Rodríguez-Fernández, OS
García-Cerda, LA
Matutes-Aquino, J
机构
[1] Ctr Invest Quim Aplicada, Saltillo 25000, Coahuila, Mexico
[2] Ctr Invest Mat Avanzados, Chihuahua, Chih, Mexico
关键词
magnetic latexes; polymers; magnetic materials; miniemulsion polymerization; magnetic measurements;
D O I
10.1016/j.jallcom.2003.09.077
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preparation of magnetic latexes using styrene monomer was carried out via the miniemulsion polymerization technique. Magnetite (Fe3O4), with an average size of 12 nm was used as magnetic particles. An organic phase was prepared dispersing the magnetite in styrene where bis(2-ethyl, hexyl) sulphosuccinate (AOT) was used as dispersant. The dispersion was then miniemulsified in water using cethyltrimethyl ammonium bromide (CTAB) as second emulsifier forming a stable emulsion. The miniemulsion polymerization was carried out at 60 degreesC and was initiated with 2.2-Azobisisobutyronitrile (AIBN). The latexes obtained were characterized by X-ray diffraction (XRD), magnetometry and transmission electron microscopy. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:87 / 89
页数:3
相关论文
共 12 条
[1]   Synthesis of ultra-fine particles of strontium hexaferrite by a modified co-precipitation method [J].
Ataie, A ;
Heshmati-Manesh, S .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1951-1955
[2]   Preparation and properties of magnetite and polymer magnetite nanoparticles [J].
Dresco, PA ;
Zaitsev, VS ;
Gambino, RJ ;
Chu, B .
LANGMUIR, 1999, 15 (06) :1945-1951
[3]  
Erdem B, 2000, J POLYM SCI POL CHEM, V38, P4431, DOI 10.1002/1099-0518(20001215)38:24<4431::AID-POLA120>3.0.CO
[4]  
2-Y
[5]   UNIFORM ENCAPSULATION OF FINE INORGANIC POWDER WITH SOAPLESS EMULSION POLYMERIZATION [J].
HASEGAWA, M ;
ARAI, K ;
SAITO, S .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (11) :3117-3125
[6]  
Hoffmann D., 2001, MAGNETOHYDRODYNAMICS, V37, P217
[7]  
KONDO A, 1994, APPL MICROBIOL BIOT, V41, P99
[8]   Preparation of ultrafine Fe3O4 particles by precipitation in the presence of PVA at high pH [J].
Lee, J ;
Isobe, T ;
Senna, M .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 177 (02) :490-494
[9]  
Schwertmann U., 1991, IRON OXIDES LAB
[10]   PREPARATION OF MONODISPERSED COLLOIDAL PARTICLES [J].
SUGIMOTO, T .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1987, 28 (01) :65-108