Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

被引：193

作者：

Zhu, Xiang ^{[1
,2
,3
]}

Mahurin, Shannon M. ^{[3
]}

An, Shu-Hao ^{[1
,2
]}

Chi-Linh Do-Thanh ^{[4
]}

Tian, Chengcheng ^{[1
,2
,3
]}

Li, Yankai ^{[1
,2
]}

Gill, Lance W. ^{[3
]}

Hagaman, Edward W. ^{[3
]}

Bian, Zijun ^{[1
,2
]}

Zhou, Jian-Hai ^{[1
,2
]}

Hu, Jun ^{[1
,2
]}

Liu, Honglai ^{[1
,2
]}

Dai, Sheng ^{[3
,4
]}

机构：

[1] E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

[2] E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China

[3] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[4] Univ Tennessee, Dept Chem, Knoxville, TN 37916 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 59期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; BENZIMIDAZOLE-LINKED POLYMERS; MICROPOROUS POLYMERS; AROMATIC FRAMEWORKS; GAS-STORAGE; NETWORKS; SELECTIVITY; ADSORPTION; SEPARATION; MEMBRANES;

D O I：

10.1039/c4cc01588f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous triazine and carbazole bifunctionalized task-specific polymer has been synthesized via a facile Friedel-Crafts reaction. The resultant porous framework exhibits excellent CO2 uptake (18.0 wt%, 273 K and 1 bar) and good adsorption selectivity for CO2 over N-2.

引用

页码：7933 / 7936

页数：4

共 25 条

[1] New insights into carbon dioxide interactions with benzimidazole-linked polymers [J].

Altarawneh, Suha ;

Behera, S. ;

Jena, Puru ;

El-Kaderi, Hani M. .

CHEMICAL COMMUNICATIONS, 2014, 50 (27) :3571-3574

[2] Copper(I)-Catalyzed Synthesis of Nanoporous Azo-Linked Polymers: Impact of Textural Properties on Gas Storage and Selective Carbon Dioxide Capture [J].

Arab, Pezhman ;

Rabbani, Mohammad Gulam ;

Sekizkardes, Ali Kemal ;

Islamoglu, Timur ;

El-Kaderi, Hani M. .

CHEMISTRY OF MATERIALS, 2014, 26 (03) :1385-1392

[3] Gas storage in porous aromatic frameworks (PAFs) [J].

Ben, Teng ;

Pei, Cuiying ;

Zhang, Daliang ;

Xu, Jun ;

Deng, Feng ;

Jing, Xiaofei ;

Qiu, Shilun .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :3991-3999

[4] Nitrogen-Containing Microporous Conjugated Polymers via Carbazole-Based Oxidative Coupling Polymerization: Preparation, Porosity, and Gas Uptake [J].

Chen, Qi ;

Liu, De-Peng ;

Luo, Min ;

Feng, Li-Juan ;

Zhao, Yan-Chao ;

Han, Bao-Hang .

SMALL, 2014, 10 (02) :308-315

[5] Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation [J].

Chen, Qi ;

Luo, Min ;

Hammershoj, Peter ;

Zhou, Ding ;

Han, Ying ;

Laursen, Bo Wegge ;

Yan, Chao-Guo ;

Han, Bao-Hang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) :6084-6087

[6] Chemical functionalization strategies for carbon dioxide capture in microporous organic polymers [J].

Dawson, Robert ;

Cooper, Andrew I. ;

Adams, Dave J. .

POLYMER INTERNATIONAL, 2013, 62 (03) :345-352

[7] Impact of Water Coadsorption for Carbon Dioxide Capture in Microporous Polymer Sorbents [J].

Dawson, Robert ;

Stevens, Lee A. ;

Drage, Trevor C. ;

Snape, Colin E. ;

Smith, Martin W. ;

Adams, Dave J. ;

Cooper, Andrew I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (26) :10741-10744

[8] Microporous organic polymers for carbon dioxide capture [J].

Dawson, Robert ;

Stoeckel, Ev ;

Holst, James R. ;

Adams, Dave J. ;

Cooper, Andrew I. .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :4239-4245

[9] Chemical tuning of CO2 sorption in robust nanoporous organic polymers [J].

Dawson, Robert ;

Adams, Dave J. ;

Cooper, Andrew I. .

CHEMICAL SCIENCE, 2011, 2 (06) :1173-1177

[10]

Du NY, 2011, NAT MATER, V10, P372, DOI [10.1038/NMAT2989, 10.1038/nmat2989]

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