Novel ring-opening reaction of tetrahydrofuran promoted by a cationic uranium amide compound

被引：25

作者：

Boisson, C ^{[1
]}

Berthet, JC ^{[1
]}

Lance, M ^{[1
]}

Nierlich, M ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA SACLAY,CRISTALLOCHIM LAB,SERV CHIM MOL,CNRS URA 331,F-91191 GIF SUR YVETTE,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 18期

关键词：

D O I：

10.1039/cc9960002129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cationic uranium amide compound [U(cp*)(2)(NMe(2))(thf)][BPh(4)] (cp* = eta-C(5)Me(5)) reacts with tetrahydrofuran (thf) in the presence of free amine as catalyst to give the heterocyclic metallacycle [(cp*)(2)U(o{CH2}(4)NMe(2){CH2}O-4)][BPh(4)]. 0.5thf; the crystal structure of the pyridine solvate is determined.

引用

页码：2129 / 2130

页数：2

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