Evaporation of WO3 on carbon nanotube films:: a new hybrid film

被引:8
作者
Bittencourt, C.
Felten, A.
Espinosa, E. H.
Ionescu, R.
Moreau, N.
Heszler, P.
Granqvist, G.
Pireaux, J-J
Llobet, E.
机构
[1] Univ Namur, LISE, B-5000 Namur, Belgium
[2] Univ Rovira & Virgili, MINOS, E-43007 Tarragona, Spain
[3] Univ Namur, RMN, B-5000 Namur, Belgium
[4] Uppsala Univ, Angstrom Lab, Dept Engn Sci, SE-75121 Uppsala, Sweden
关键词
D O I
10.1088/0964-1726/15/6/007
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Hybrid WO3-CNT ( carbon nanotube) films were prepared in two steps: in the first step, the drop coating method was employed for coating silicon substrates with a MWCNT (multiwalled CNT) film prepared with oxygen plasma functionalized MWCNTs; in the second step, a layer of WO3 nanoparticles was deposited over the MWCNT film by using an advanced gas deposition unit. The WO3 nanoparticles are formed by condensation. SEM images show that the morphology of the hybrid films is characterized by an overlayer formed from WO3 particles anchored at the surface of a well-dispersed MWCNT underlayer. TEM images show that the hybrid films are composed of a WO3 matrix supported through a dispersed mesh of CNTs-the CNTs act as internal pillars. This morphology increases the surface area for gas interaction.
引用
收藏
页码:1555 / 1560
页数:6
相关论文
共 33 条
[1]   X-ray photoemission spectroscopy study of fluorinated single-walled carbon nanotubes [J].
An, KH ;
Heo, JG ;
Jeon, KG ;
Bae, D ;
Jo, CS ;
Yang, CW ;
Park, CY ;
Lee, YH ;
Lee, YS ;
Chung, YS .
APPLIED PHYSICS LETTERS, 2002, 80 (22) :4235-4237
[2]   Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: A bucky paper electrode [J].
Bahr, JL ;
Yang, JP ;
Kosynkin, DV ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6536-6542
[3]   Chemically functionalized single-walled carbon nanotubes as ammonia sensors [J].
Bekyarova, E ;
Davis, M ;
Burch, T ;
Itkis, ME ;
Zhao, B ;
Sunshine, S ;
Haddon, RC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (51) :19717-19720
[4]   High-resolution photoelectron spectroscopy studies on WO3 films modified by Ag addition [J].
Bittencourt, C ;
Felten, A ;
Mirabella, F ;
Ivanov, P ;
Llobet, E ;
Silva, MAP ;
Nunes, LAO ;
Pireaux, JJ .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (43) :6813-6822
[5]   Influence of the catalytic introduction procedure on the nano-SnO2 gas sensor performances -: Where and how stay the catalytic atoms? [J].
Cabot, A ;
Diéguez, A ;
Romano-Rodríguez, A ;
Morante, JR ;
Bârsan, N .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 79 (2-3) :98-106
[6]   Insertion of thin films of WO3 in liquid crystal cells [J].
Cazzanelli, E ;
Scaramuzza, N ;
Strangi, G ;
Versace, C ;
Pennisi, A ;
Simone, F .
ELECTROCHIMICA ACTA, 1999, 44 (18) :3101-3109
[7]   Ag dopedWO3-based powder sensor for the detection of NO gas in air [J].
Chen, L ;
Tsang, SC .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 89 (1-2) :68-75
[8]   Plasma activation of carbon nanotubes for chemical modification [J].
Chen, QD ;
Dai, LM ;
Gao, M ;
Huang, SM ;
Mau, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (03) :618-622
[9]   EFFECTS OF BARRIER HEIGHT INHOMOGENEITY ON CORE-LEVEL PHOTOEMISSION FROM CLEAN AND METAL-COVERED SEMICONDUCTOR SURFACES [J].
CIMINO, R ;
GIARANTE, A ;
HORN, K ;
PEDIO, M .
EUROPHYSICS LETTERS, 1995, 32 (07) :601-606
[10]   WO3 thin films by sol-gel for electrochromic applications [J].
Cremonesi, A ;
Bersani, D ;
Lottici, PP ;
Djaoued, Y ;
Ashrit, PV .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 345 :500-504