The nonradiative decay of the allyl radical excited B (2)A(1) state studied by picosecond time-resolved photoelectron spectroscopy

被引：35

作者：

Schultz, T ^{[1
]}

Fischer, I ^{[1
]}

机构：

[1] ETH ZURICH,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 19期

关键词：

D O I：

10.1063/1.475121

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nonradiative decay rates of the vibrational ground state and the v(7) fundamental ill the electronically excited B (2)A(1) state of the allyl radical, C3H5, are studied by picosecond time-resolved pump-probe photoelectron spectroscopy. The states decay by internal conversion with a time constant of 20 and 16 ps, respectively. (C) 1997 American Institute of Physics.

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页码：8197 / 8200

页数：4

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