FT-IR and NMR study of tris(oxaalkyl) borates and their complexes with HAuCl4

被引：13

作者：

Brzezinski, B

Gierczyk, B

Rózalski, B

Wojciechowski, G

Schroeder, G

Zundel, G

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

[2] Univ Munich, Inst Phys Chem, D-80333 Munich, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2000年 / 519卷

关键词：

tris(oxaalkyl) berates; proton polarizability; hydrogen bond; collective hydrogen bond; FT-IR spectroscopy; H-1 and C-13 NMR;

D O I：

10.1016/S0022-2860(99)00281-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three tris(oxaalkyl) berates and their complexes with HAuCl4 were studied by FT-IR, H-1 and C-13 NMR spectroscopy. Continuous absorption in the FT-IR spectra of the complexes testifies the formation of proton channels showing large proton polarizability. The shape of the proton potential is discussed on the basis of the NMR data. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：119 / 123

页数：5

共 8 条

[1] THE F-O COMPLEX OF THE ATP SYNTHASE OF ESCHERICHIA-COLI CONTAINS A PROTON PATHWAY WITH LARGE PROTON POLARIZABILITY CAUSED BY COLLECTIVE PROTON FLUCTUATION [J].