Transition metal halide salts of 2-amino-3-methylpyridine:: synthesis, crystal structures and magnetic properties of (3-MAP)2CuX4 [3-MAP=2-amino-3-methylpyridinium;: X = Cl, Br]

被引：57

作者：

Coffey, TJ

Landee, CP

Robinson, WT

Turnbull, MM ^{[1
]}

Winn, M

Woodward, FM

机构：

[1] Clark Univ, Carlson Sch Chem & Biochem, Worcester, MA 01610 USA

[2] Clark Univ, Dept Phys, Worcester, MA 01610 USA

[3] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

INORGANICA CHIMICA ACTA | 2000年 / 303卷 / 01期

基金：

美国国家科学基金会;

关键词：

crystal structures; magnetic properties; copper complexes; halide complexes;

D O I：

10.1016/S0020-1693(99)00517-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuX2. nH(2)O with HX [X = Cl, Br] and 2-amino-3-methylpyridine in aqueous solution gave compounds of the formula (3-MAP)(2)(CuX4) [3-MAP = 2-amino-3-methylpyridinium]. The compounds have been characterized by single-crystal X-ray diffraction. The complexes crystallize as salts with the 3-MAP cations separating layers of tetrahalometallate anions. Both compounds have two independent molecules in their asymmetric units. Weak antiferromagnetic interactions are observed, which suggest a primarily low-dimensional magnetic exchange network. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：54 / 60

页数：7

共 19 条

[1] New square S=1/2 Heisenberg antiferromagnetic lattices: Pyridinium tetrahalocuprates and bispyrazinecopper(II) tetrafluoroborate [J].