Metal directed assemblies of a dipeptide:: Formation of β-pleated sheets

被引：25

作者：

Barooah, Nilotpal ^{[1
]}

Sarma, Rupam J. ^{[1
]}

Baruah, Jubaraj B. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 15卷 / 15期

关键词：

hydrogen bonding; self-assembly; dipeptide; beta-sheets; coordination polymer;

D O I：

10.1002/ejic.200600219

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of N-phthaloylglycylglycine and its complexes with copper(II) and zinc(II) are studied. The N-phthaloylglycylglycinato copper(II) complex has a polymeric structure formed by bridging carboxylates. The corresponding N-phthaloylglycylglycinato zinc(II) complex is monomeric. Both the metal complexes have self-assembled hydrogen-bonded structures in which dipeptide ligand adopt pleated conformations. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.

引用

页码：2942 / 2946

页数：5

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