Maya blue paint: An ancient nanostructured material

被引:168
作者
JoseYacaman, M
Rendon, L
Arenas, J
Puche, MCS
机构
[1] INST NACL INVEST NUCL,SALAZAR 52045,MEXICO
[2] INST NACL ANTROPOL & HIST,MUSEO NACL ANTROPOL,MEXICO CITY 11560,DF,MEXICO
关键词
D O I
10.1126/science.273.5272.223
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Maya blue paint was often used in Mesoamerica. The origin of its color and its resistance to acids and biocorrosion have not been fully understood. High-resolution transmission electron microscopy, electron energy loss spectroscopy, and x-ray microanalysis studies of authentic samples show that palygorskite crystals in the paint form a superlattice that probably occurs as a result of mixing with indigo molecules. An amorphous silicate substrate contains inclusions of metal nanoparticles encapsulated in the substrate and oxide nanoparticles on the surface. The beautiful tone of the color is obtained only when both the particles and the superlattice are present.
引用
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页码:223 / 225
页数:3
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