Novel palladium catalyzed dehydrogenation of alpha-hydrazinonitriles to hydrazonoyl cyanides using cyclopentene. Synthesis of 1H-pyrazole-4-carboxylate

被引:11
作者
Kim, YH
Choi, JY
机构
[1] Department of Chemistry, Korea Adv. Inst. of Sci. and T., Yusong Gu, Taejon 305-701, 373-1, Kusong Dong
关键词
D O I
10.1016/S0040-4039(96)02028-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium charcoal catalyzed dehydrogenation of alpha-hydrazinonitriles has been found to give hydrazonoyl cyanides in the presence of cyclopentene in high yields, which was applied to the synthesis of 1H-pyrazole-4-carboxylates. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:8771 / 8774
页数:4
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