Electroluminescence from a new distyrylbenzene based triazine dendrimer

被引:76
作者
Lupton, JM
Hemingway, LR
Samuel, IDW
Burn, PL
机构
[1] Univ Durham, Dept Phys, Durham DH1 3LE, England
[2] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England
关键词
D O I
10.1039/a908816d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have synthesised a new distyrylbenzene cored dendrimer which utilises triazine rings to link the surface groups. It was found that methoxy surface groups were sufficient to give the dendrimer good solubility and good quality thin films could be prepared by spin-coating from solution. The dendrimer was luminescent both in solution and the solid state with the emission occurring from the core. The photoluminescence quantum yield was determined to be 31 +/- 3% in the solid state. The dendrimer was incorporated into a single layer light-emitting diode (ITO/dendrimer/Ca) and was found to emit blue light with an external quantum efficiency of 0.003%.
引用
收藏
页码:867 / 871
页数:5
相关论文
共 25 条
[1]  
[Anonymous], 1959, S TRIAZINES DERIVATI
[2]   Efficient synthesis of starburst oxadiazole compounds [J].
Bettenhausen, J ;
Strohriegl, P .
ADVANCED MATERIALS, 1996, 8 (06) :507-+
[3]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[4]  
CHEN TQ, 1997, PHOSPHORUS SULFUR, V125, P1
[5]  
DANDLIKER PJ, 1994, ANGEW CHEM INT EDIT, V33, P1739, DOI 10.1002/anie.199417391
[6]  
DENNIS N, 1977, J CHEM SOC P1, P1931
[7]  
DRESNER J, 1969, RCA REV, V30, P322
[8]   Synthesis and characterization of aromatic poly( 1,3,5-triazine-ether)s for electroluminescent devices [J].
Fink, R ;
Frenz, C ;
Thelakkat, M ;
Schmidt, HW .
MACROMOLECULES, 1997, 30 (26) :8177-8181
[9]   ANGULAR-DEPENDENCE OF THE EMISSION FROM A CONJUGATED POLYMER LIGHT-EMITTING DIODE - IMPLICATIONS FOR EFFICIENCY CALCULATIONS [J].
GREENHAM, NC ;
FRIEND, RH ;
BRADLEY, DDC .
ADVANCED MATERIALS, 1994, 6 (06) :491-494
[10]   MEASUREMENT OF ABSOLUTE PHOTOLUMINESCENCE QUANTUM EFFICIENCIES IN CONJUGATED POLYMERS [J].
GREENHAM, NC ;
SAMUEL, IDW ;
HAYES, GR ;
PHILLIPS, RT ;
KESSENER, YARR ;
MORATTI, SC ;
HOLMES, AB ;
FRIEND, RH .
CHEMICAL PHYSICS LETTERS, 1995, 241 (1-2) :89-96