Selective extraction of Fe3+ cation by callxarene-based cyclic ligands

被引：33

作者：

Yilmaz, M

Deligoz, H

机构：

[1] Department of Chemistry, Selçuk University

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 1996年 / 31卷 / 17期

关键词：

D O I：

10.1080/01496399608001055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selective liquid-liquid extraction of Fe3+ cation from the aqueous phase to the organic phase was carried out by using p-tert-butylcalix[4]arene [L(1)], calix[4]arene [L(2)], p-nitro-calix[4]arene [L(3)], calix[4]arene p-sulfonic acid [L(4)], p- (diethylamino)methylcalix [4] arene [L(5)], tetramethyl-p-tert-butylcalix[4]arene tetraketone [L(6)], 25,27-dimethyl-26, 28-dihydroxy-p-tert-butylcalix[4]arene diketone [L(7)], calix[4] arene-bearing dioxime group on the lower rim [L(8)], and a monooxime [L(9)]. The effect of varying pH upon the extraction ability of calixarenes substituted with electron-donating and electron-withdrawing groups at their p-position was examined. Observed results were compared with those found for unsubstituted calix[4]arene.

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页码：2395 / 2402

页数：8

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