Porphyrin-perylene bisimide dyads and triads: Synthesis and optical and coordination properties

被引：59

作者：

You, CC ^{[1
]}

Wurthner, F ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 14期

关键词：

D O I：

10.1021/ol049206l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel porphyrin perylene dyad and triad dyes have been prepared by the coupling of aminophenyltrisphenylporphyrin and tetraphenoxy-substituted perylenetetracarboxylic acid bisanhydrides in a one-step synthesis. Fluorescence spectra of these compounds reveal features that are attributable to emission of perylene bisimides as well as porphyrin excited states. The self-assembly behavior of zinc-metalated compounds with 4,4'-bipyridine and diazabenzoperylene has been investigated by H-1 NMR spectroscopy in CDCl3, showing that oligomeric zigzag assemblies are formed.

引用

页码：2401 / 2404

页数：4

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