Reaction of nickelocene with 1,3-dimesitylimidazolium chloride

被引：106

作者：

Abernethy, CD ^{[1
]}

Cowley, AH ^{[1
]}

Jones, RA ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 596卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

cyclopentadienyl; nickel; chlorine; carbene complex; imidazolium;

D O I：

10.1016/S0022-328X(99)00557-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of nickelocene with 1,3-dimesitylimidazolium chloride affords the corresponding carbene complex, (eta(5)-C5H5)NiCl(carbene) (5). The structure of 5 was determined by X-ray crystallography. The distorted trigonal planar nickel atom is attached to an eta(5)-Cp, a carbene, and a chloride ligand. Compound 5 reacts with MeLi to afford (eta(5)-C5H5)Ni(Me)(carbene). (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：3 / 5

页数：3

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