Cation and anion electronic excitations in MgO and BaF2 crystals under excitation by photons up to 75 eV

被引:13
作者
Kirm, M
Vielhauer, S
Zimmerer, G
Lushchik, A
Lushchik, C
机构
[1] Univ Hamburg, Inst Expt Phys 2, D-22761 Hamburg, Germany
[2] Univ Tartu, Inst Phys, EE-51014 Tartu, Estonia
关键词
D O I
10.1142/S0218625X02003810
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The creation of primary and secondary cation excitations was investigated for MgO and BaF2 crystals using the energy- and time-resolved luminescence method. It was shown that the primary cation excitations in MgO created by photons of 50-65 eV decay with the formation of anion free excitons and electron-hole pairs. The formation of secondary cation holes by hot photoelectrons in the Ba2+ 5p shell causes the increase of cross-luminescence intensity whereas the creation of neither primary nor secondary cation excitons causes the appearance of cross-luminescence in BaF2.
引用
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页码:1363 / 1368
页数:6
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