Electrochemical behavior of olivine-type LiMnPO4 in aqueous solutions

被引：46

作者：

Minakshi, Manickam ^{[1
]}

Singh, Pritam

Thurgate, Stephen

Prince, Kathryn

机构：

[1] Murdoch Univ, Div Sci & Engn, Murdoch, WA 6150, Australia

[2] Australian Nucl Sci & Technol Org, Lucas Heights, NSW 2234, Australia

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2006年 / 9卷 / 10期

关键词：

D O I：

10.1149/1.2236379

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical behavior of olivine-type lithium manganese phosphate (LiMnPO4) as a cathode material was investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type LiMnPO4 and the products which are formed on its oxidation and subsequent reduction were studied. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and secondary ion mass spectrometry were used for these investigations. LiMnPO4 was found to be reversibly delithiated/lithiated on electro-oxidation/reduction. (c) 2006 The Electrochemical Society.

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页码：A471 / A474

页数：4

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