Sol gel-immobilised terbium complexes for luminescent sensing of dissolved oxygen by analysis of emission decay

被引:41
作者
Blair, S [1 ]
Kataky, R [1 ]
Parker, D [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
D O I
10.1039/b110743g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cationic terbium complexes bearing an N-methylphenanthridinium chromophore have been incorporated in sol gel thin films and their response characteristics analysed with respect to variations in dissolved oxygen concentration. Analysis of the emission lifetime decay curves (547nm) has allowed a linear calibration model to be defined over an oxygen concentration range from zero to 0.5 mM (H2O, 295 K).
引用
收藏
页码:530 / 535
页数:6
相关论文
共 34 条
  • [1] Photoluminescent oxygen sensing using tris(acethylacetonato) 1,10-phenanthroline terbium(III) complex doped on alumina film
    Amao, Y
    Okura, I
    Miyashita, T
    [J]. CHEMISTRY LETTERS, 2000, (11) : 1286 - 1287
  • [2] Platinum porphyrin embedded in poly(1-trimethylsilyl-1-propyne) film as an optical sensor for trace analysis of oxygen
    Amao, Y
    Asai, K
    Okura, I
    Shinohara, H
    Nishide, H
    [J]. ANALYST, 2000, 125 (11) : 1911 - 1914
  • [3] Optical oxygen detection based an luminescence change of metalloporphyrins immobilized in poly(isobutylmethacrylate-co-trifluoroethylmethacrylate) film
    Amao, Y
    Miyashita, T
    Okura, I
    [J]. ANALYTICA CHIMICA ACTA, 2000, 421 (02) : 167 - 174
  • [4] Thenoyltrifluoroacetonato 1,10-phenanthroline europium (III) complex immobilized in fluoropolymer film as optical oxygen sensing material
    Amao, Y
    Okura, I
    Miyashita, T
    [J]. CHEMISTRY LETTERS, 2000, (08) : 934 - 935
  • [5] Novel optical oxygen sensing device: a thin film of a palladium porphyrin with a long alkyl chain on an alumina plate
    Amao, Y
    Miyakawa, K
    Okura, I
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (02) : 305 - 308
  • [6] Optical oxygen sensing based on the luminescence quenching of europium(III) complex immobilized in fluoropolymer film
    Amao, Y
    Okura, I
    Miyashita, T
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (12) : 2663 - 2668
  • [7] Porphyrin sensitization of circularly polarised near-IR lanthanide luminescence: enhanced emission with nucleic acid binding
    Beeby, A
    Dickins, RS
    FitzGerald, S
    Govenlock, LJ
    Maupin, CL
    Parker, D
    Riehl, JP
    Siligardi, G
    Williams, JAG
    [J]. CHEMICAL COMMUNICATIONS, 2000, (13) : 1183 - 1184
  • [8] Photochemical investigations of functionalised 1,4,7,10-tetraazacyclododecane ligands incorporating naphthyl chromophores
    Beeby, A
    Parker, D
    Williams, JAG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (08): : 1565 - 1579
  • [9] Narrow-range optical pH sensors based on luminescent europium and terbium complexes immobilized in a sol gel glass
    Blair, S
    Lowe, MP
    Mathieu, CE
    Parker, D
    Senanayake, PK
    Kataky, R
    [J]. INORGANIC CHEMISTRY, 2001, 40 (23) : 5860 - 5867
  • [10] Chiroptical, ESMS and NMR spectroscopic study of the interaction of enantiopure lanthanide complexes with selected self-complementary dodecamer oligonucleotides
    Bobba, G
    Dickins, RS
    Kean, SD
    Mathieu, CE
    Parker, D
    Peacock, RD
    Siligardi, G
    Smith, MJ
    Williams, JAG
    Geraldes, CFGC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, Royal Society of Chemistry (09): : 1729 - 1737